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酮肟在具有极性的溶剂存在下,发生分子结构的重排,在环已酮肟的情况下,则是氮原子转移至环中从而使环链增大:
Ketoxime rearranges in the presence of a polar solvent, and in the case of cyclohexanone oxime, the nitrogen atom is transferred to the ring to increase the chain length: