【摘 要】
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The first example of Rh-catalyzed kinetic resolution of 1,3-disubstituted allene-1,3-dienes involving intramolecular[4+2]-cycloaddition has been developed.Follo
【机 构】
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Research Center for Molecular Recognition and Synthesis, Department of Chemistry, Fudan University,
论文部分内容阅读
The first example of Rh-catalyzed kinetic resolution of 1,3-disubstituted allene-1,3-dienes involving intramolecular[4+2]-cycloaddition has been developed.Followed by C=C isomerization,the reaction finally afforded aza-[4.3.0]bicyclic compounds with a very high enantio-and E-selectivity.The mechanism has been unveiled by careful control experiments.The synthetic potentials of highly enantioenriched bicyclic products have also been demonstrated.
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