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本文由气相色谱法的理论中部分基本内容引出Jan Ceulemans对气相色谱法参数的新的研究。Jan Ceulemans以峰宽和保留时间的准线性关系为基础,提出用两个新参数N_(inf)(最大分配比即最大分离度下的塔板数)和tq(校正保留时间的修正值)表示柱特性,由此推导出的计算塔板数、分离度和最小操作时间的方程式不含有k值(分配比),基于这些方程式,使有可能选择出较理想的柱和柱操作条件。
In this paper, a new study of gas chromatography parameters by Jan Ceulemans is drawn from some basic contents of gas chromatography theory. Based on the quasi-linear relationship between peak width and retention time, Jan Ceulemans proposed two new parameters, N inf (the maximum distribution ratio, the number of plates at maximum resolution) and tq (corrected value of corrected retention time) Based on the column characteristics, the equation for calculating plate number, resolution, and minimum operating time derived from this does not contain the value of k (distribution ratio). Based on these equations, it is possible to select the ideal column and column operating conditions.