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米哈依尔·伊万诺维奇·康诺瓦洛夫(МнхаилИваповичКоновалов)在研究一系列环烃之后,打算氧化从石油中提出来的一种环烃——壬环烷C_9H_(18)(三甲基环己烷)的侧链,为此他把壬环烷与比重1.115即相当于25％的HNO_3一同放到封闭管中加热到120—150°;他发现在反应产物中除了氧化产物外,还有硝基衍生物即硝基壬环烷C_9H_(17)NO_2。这种观察成为硝酸对饱和烃的作用的系统研究的开端。曾经发现,烃类与比重1.075即相当于12.7％的HNO_3在封闭管中加热当温度不超过
After studying a series of cyclic hydrocarbons, Mikhail Ivanovich Konovalov intended to oxidize a cyclic hydrocarbon, nonanecane C_9H_ (18) (tris Methylcyclohexane), for which he heated nonane-cycloalkane to a closed tube with a specific gravity of 1.115, which corresponds to 25% HNO 3, to 120-150 °; he found that in addition to the oxidation products , As well as the nitro derivative nitronaphthalene C_9H_ (17) NO_2. This observation turns out to be the beginning of a systematic investigation of the effect of nitric acid on saturated hydrocarbons. It has been found that hydrocarbons with a specific gravity of 1.075, or 12.7% of HNO 3, are heated in a closed tube when the temperature does not exceed