人类使用铜制剂已有两百多年的历史,铜制剂堪称是杀菌剂中的“百年老字号”。1761年,人们用硫酸铜处理小麦种子防治腥黑穗病。1800年,法国发现波尔多液的化学性质。1882年,法国波尔多大学教授米拉德发现波尔多液防治葡萄霜霉病的作用。1922年,哈利尔报道硫酸铜处理水坑防治钉螺 For more than two hundred years of human use of copper preparations, copper preparations have been described as “century-old” in fungicides. In 1761, people treated the seeds of wheat with copper sulfate to prevent the disease. In 1800, France discovered the chemical properties of Bordeaux mixture. In 1882, Milad, a professor at the University of Bordeaux, France, discovered the effect of Bordeaux mixture against grape downy mildew. In 1922, Khalil reported that copper sulfate treatment of potholes to control snails